Current status of research on nanobubbles in particle flotation

Jian Chen, Jun Chen, Yali Cheng
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Abstract

Froth flotation, as one of the most widely used separation approaches in mineral processing, is commonly used to recover valuable components from minerals. However, maintaining high flotation efficiencies is a serious challenge for conventional froth flotation in the face of decreasing particle size of the minerals to be sorted. To date, there have been plenty of reports on the software of nano-bubbles (NBS) in flotation, and the experimental consequences show that nano-bubbles' introduction has given rise to improvement's different grades in the recovery of varieties of minerals, which highlights the great potential of nano-bubbles for mineral flotation. Nanobubbles have smaller bubble radii and unusually high stability compared to conventional flotation bubbles, and their related behavior in flotation has been a hot research topic. This paper reviews some of the methods of preparing nanobubbles, equipment techniques for characterizing nanobubbles, factors affecting their stability, and some of the popular doctrines. In particular, the reinforcing mechanism of nanobubbles in the particle flotation process is discussed, first, the nanobubbles improve the electrostatic attractiveness with the particles by achieving the charge inversion while the nanobubbles that was adsorbed on the particles' surface will cover a share of the charge, which decreases the electrostatic repulsive force between the particles; and second, the nanobubbles can act as a bridge between the surfaces of the two particles, which advances the agglomeration between the particles. This review aims to be able to further advance the research related to the industrialization of nanobubbles.
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颗粒浮选中的纳米气泡研究现状
浮选是矿物加工中应用最广泛的分离方法之一,通常用于从矿物中回收有价值的成分。然而,面对待选矿物粒度的不断减小,保持高浮选效率是传统泡沫浮选法面临的严峻挑战。迄今为止,已有大量关于纳米气泡(NBS)在浮选中的应用的报道,实验结果表明,纳米气泡的引入使各种矿物的回收率得到了不同程度的提高,凸显了纳米气泡在矿物浮选中的巨大潜力。与传统浮选气泡相比,纳米气泡具有更小的气泡半径和异常高的稳定性,其在浮选中的相关行为一直是研究的热点。本文综述了纳米气泡的一些制备方法、表征纳米气泡的设备技术、影响纳米气泡稳定性的因素以及一些流行的学说。其中特别讨论了纳米气泡在颗粒浮选过程中的强化机理:首先,纳米气泡通过实现电荷反转来提高与颗粒的静电吸引力,同时吸附在颗粒表面的纳米气泡会覆盖一部分电荷,从而减小颗粒间的静电排斥力;其次,纳米气泡可以作为两个颗粒表面之间的桥梁,促进颗粒间的团聚。本综述旨在进一步推动与纳米气泡产业化相关的研究。
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