Use of Biosourced Molecules as Liquid Organic Hydrogen Carriers (LOHC) and for Circular Storage

Reactions Pub Date : 2024-02-07 DOI:10.3390/reactions5010008
Nelson Alexis Bermudez Aponte, Valérie Meille
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Abstract

The use of Liquid Organic Hydrogen Carriers (LOHC) is one of the potential options to store hydrogen. Today, the vast majority of compounds used as LOHC come from the oil industry. Using biosourced LOHC would be a step forward in the development of this CO2-free solution. This article looks at LOHC candidates that can be obtained from biomass. The special case of formic acid and methanol, which do not fall within the definition of LOHC, is also considered. The synthesis of alcohols, polyols, amines, aminoalcohols and N-heterocyclic compounds from biosourced compounds is reviewed.
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利用生物源分子作为液态有机氢载体(LOHC)并进行循环储存
使用液态有机载氢体(LOHC)是储存氢气的潜在选择之一。目前,绝大多数用作液态有机氢载体的化合物都来自石油工业。使用生物来源的液态有机氢载体将是在开发这种无二氧化碳解决方案方面向前迈出的一步。本文探讨了可从生物质中获得的候选低浓度氢。此外,还考虑了甲酸和甲醇的特殊情况,它们不属于 LOHC 的定义范围。文章回顾了从生物源化合物中合成醇、多元醇、胺、氨基醇和 N-杂环化合物的过程。
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