Calibration of a passive sampling device for the determination of nitrogen dioxide in ambient air

Abstract

Nitrogen dioxide (NO₂), a common air pollutant, has been widely admitted to be harmful to both the environment and human health, demanding its well-control procedure and corresponding quantification. In this study, NO₂ in ambient air was collected by a passive sampling method using the Willems badge diffusive sampler, followed by a derivatization step with the Griess-Saltzman solution, and analyzed by ultraviolet-visible (UV–vis) spectroscopy at 543 nm. The device can be utilized for 168 h of continuous field sampling. The experimental sampling rate (K_e) of (4.02 ± 0.29) × 10⁻³ m³ h ^{− 1} with a relative standard deviation (% RSD) of 9.6 % was determined by conducting parallel experiments between an active sampling method (ISO 6768:1998) and the Willems samplers. After exposure time, samplers could be stored for two weeks in a refrigerator at 4 °C before analyzing. The studied passive diffusive sampler was simple, low-cost, easy to reuse; permitted determining the average concentration of NO₂ in ambient air. The average NO₂ concentrations for 2-hour to 4-hour sampling periods at different studied sampling sites in Ho Chi Minh city (Vietnam) were ranged from 11.5 to 189 μg m ^{− 3}.