Continuing long-term expansion of low-oxygen conditions in the Eastern Gulf of Finland

IF 4.6 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2024-01-01 DOI:10.1016/j.oceano.2024.02.002
Stella-Theresa Stoicescu , Laura Hoikkala , Vivi Fleming , Urmas Lips
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Abstract

To develop an oxygen indicator for the eastern part of the Gulf of Finland (EGOF), a dataset covering 1900–2021 was compiled. The analysis revealed a long-term declining trend in dissolved oxygen concentrations in the EGOF deep layer of 0.022 mg L–1 a–1 and multi-decadal variations associated with the observed changes in hydrographic conditions. About 27% of the decline in oxygen concentrations for 1900–2021 and 40% for 1990–2021 can be explained by the decrease in solubility due to the temperature increase and changes in hydrographic conditions. The water volume and bottom area under low oxygen conditions in 2016–2021, characterized by dissolved oxygen concentrations <= 6 mg L–1, have increased, compared to the selected reference period with almost no human impact in the 1920s–1950s, from 9.8 km3 to 78.0 km3 (from 2.6% to 20.9% of the EGOF total volume) and from 1190 km2 to 4950 km2 (from 13.4% to 56.0% of the EGOF total area), respectively. The environmental status of the EGOF was assessed as not good based on the introduced oxygen indicator. We conclude that, in the long-term, low oxygen conditions have expanded mostly due to the excess load and accumulation of nutrients in the system and temperature-related changes in biogeochemical processes and fluxes. However, on a decadal scale, changes in hydrographic conditions, i.e. stratification and mixing, can significantly impact the sub-surface oxygen conditions in the EGOF and similar estuarine basins.

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东芬兰湾低氧条件长期持续扩大
为开发芬兰湾东部地区(EGOF)的氧气指标,编制了 1900-2021 年的数据集。分析结果表明,芬兰湾东部深层溶解氧浓度长期呈下降趋势,降幅为 0.022 mg L a,并出现了与观测到的水文条件变化相关的多年代变化。1900-2021 年氧气浓度下降的 27%和 1990-2021 年氧气浓度下降的 40%可以用温度升高和水文条件变化导致的溶解度下降来解释。与选定的几乎没有人类影响的 20 世纪 20 年代至 50 年代参照期相比,2016-2021 年处于低氧条件(溶解氧浓度小于 6 毫克升)下的水量和水底面积有所增加,分别从 9.8 千米增至 78.0 千米(从占 EGOF 总水量的 2.6%增至 20.9%)和从 1190 千米增至 4950 千米(从占 EGOF 总面积的 13.4%增至 56.0%)。根据引入的氧气指标,EGOF 的环境状况被评估为不佳。我们的结论是,从长期来看,低氧状况的扩大主要是由于系统中营养物质的过量负荷和积累,以及生物地球化学过程和通量中与温度有关的变化。然而,在十年尺度上,水文条件(即分层和混合)的变化会对 EGOF 和类似河口盆地的次表层氧气条件产生重大影响。
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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
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