{"title":"Kinetic Study of the Synthesis of a Fullerene Derivative Containing a Diterpene Fragment","authors":"","doi":"10.1007/s10553-024-01650-9","DOIUrl":null,"url":null,"abstract":"<p>Results are given for a kinetic study of the synthesis of a new fullerene derivative containing a diterpene fragment obtained using HPLC and subsequent mathematical modelling. Kinetic and activation parameters were found for the cyclopropanation of fullerene using the Bingel procedure and a reaction mechanism was proposed. The optimal synthesis conditions were found to entail a slight excess of a chlorine‑containing cyclopropanation agent and carrying out the reaction at room temperature.</p>","PeriodicalId":9908,"journal":{"name":"Chemistry and Technology of Fuels and Oils","volume":"123 1","pages":""},"PeriodicalIF":0.6000,"publicationDate":"2024-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry and Technology of Fuels and Oils","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1007/s10553-024-01650-9","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
Abstract
Results are given for a kinetic study of the synthesis of a new fullerene derivative containing a diterpene fragment obtained using HPLC and subsequent mathematical modelling. Kinetic and activation parameters were found for the cyclopropanation of fullerene using the Bingel procedure and a reaction mechanism was proposed. The optimal synthesis conditions were found to entail a slight excess of a chlorine‑containing cyclopropanation agent and carrying out the reaction at room temperature.
期刊介绍：
Chemistry and Technology of Fuels and Oils publishes reports on improvements in the processing of petroleum and natural gas and cracking and refining techniques for the production of high-quality fuels, oils, greases, specialty fluids, additives and synthetics. The journal includes timely articles on the demulsification, desalting, and desulfurizing of crude oil; new flow plans for refineries; platforming, isomerization, catalytic reforming, and alkylation processes for obtaining aromatic hydrocarbons and high-octane gasoline; methods of producing ethylene, acetylene, benzene, acids, alcohols, esters, and other compounds from petroleum, as well as hydrogen from natural gas and liquid products.
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