Ex-situ ChloGen: A facile and straightforward entry to Aryl-IF4 compounds

IF 1.7 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Journal of Fluorine Chemistry Pub Date : 2024-03-27 DOI:10.1016/j.jfluchem.2024.110276
Karim Ullah , Reza Kordnezhadian , Joachim Demaerel , Wim M. De Borggraeve , Ermal Ismalaj
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Abstract

In this work, we present a new method for the facile preparation of aryl-IF4 compounds using KF and ex situ generated chlorine gas within a two-chamber reactor setup. Notably, the process stands out for its simplicity by omitting the use of specialized equipment and generating less chemical waste than the previously reported works. While demonstrating high efficiency at room temperature, the novel approach provides access to a diverse array of products with moderate to excellent yields.

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原位 ChloGen:简单直接地进入芳基-IF4化合物
在这项工作中,我们提出了一种在双室反应器装置中使用 KF 和原位生成的氯气轻松制备芳基-IF4 化合物的新方法。值得注意的是,与之前报道的作品相比,该方法无需使用专门设备,产生的化学废物也更少,因此非常简单。这种新方法在室温下表现出很高的效率,同时还能以中等到极高的产率获得多种产品。
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来源期刊
Journal of Fluorine Chemistry
Journal of Fluorine Chemistry 化学-无机化学与核化学
CiteScore
3.80
自引率
10.50%
发文量
99
审稿时长
33 days
期刊介绍: The Journal of Fluorine Chemistry contains reviews, original papers and short communications. The journal covers all aspects of pure and applied research on the chemistry as well as on the applications of fluorine, and of compounds or materials where fluorine exercises significant effects. This can include all chemistry research areas (inorganic, organic, organometallic, macromolecular and physical chemistry) but also includes papers on biological/biochemical related aspects of Fluorine chemistry as well as medicinal, agrochemical and pharmacological research. The Journal of Fluorine Chemistry also publishes environmental and industrial papers dealing with aspects of Fluorine chemistry on energy and material sciences. Preparative and physico-chemical investigations as well as theoretical, structural and mechanistic aspects are covered. The Journal, however, does not accept work of purely routine nature. For reviews and special issues on particular topics of fluorine chemistry or from selected symposia, please contact the Regional Editors for further details.
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