K. N’dri, B. Dally, C. Vamoussa, D. Houphouët-Boigny
{"title":"Studies of Sb2S3-As2S3 glasses by quenching methods and Raman spectroscopy","authors":"K. N’dri, B. Dally, C. Vamoussa, D. Houphouët-Boigny","doi":"10.15251/cl.2024.213.255","DOIUrl":null,"url":null,"abstract":"Glasses of Sb2S3-As2S3 system with nominal composition of As0,4xSb0,4(100-x)S60 (where x= 10, 25, 50, 75 and 100 mol% As2S3) were investigated by different quenching methods and Raman spectroscopy. All studied samples were in the vitreous state. The average coordination number (Z), being equal to 2.4, has indicated that the numbers of neighbors of non-chalcogens (As and Sb) and chalcogens (S and Te) atoms were respectively 3 and 2. These coordination numbers were conditions fulfilled by the atoms to obtain vitreous materials. The vibrations of the SbS3 and AsS3 structural units dominated the Raman spectra of the studied Sb2S3-As2S3 glasses.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":"119 19","pages":""},"PeriodicalIF":17.7000,"publicationDate":"2024-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.15251/cl.2024.213.255","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Glasses of Sb2S3-As2S3 system with nominal composition of As0,4xSb0,4(100-x)S60 (where x= 10, 25, 50, 75 and 100 mol% As2S3) were investigated by different quenching methods and Raman spectroscopy. All studied samples were in the vitreous state. The average coordination number (Z), being equal to 2.4, has indicated that the numbers of neighbors of non-chalcogens (As and Sb) and chalcogens (S and Te) atoms were respectively 3 and 2. These coordination numbers were conditions fulfilled by the atoms to obtain vitreous materials. The vibrations of the SbS3 and AsS3 structural units dominated the Raman spectra of the studied Sb2S3-As2S3 glasses.
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
