Energy Levels and Transition Data of Cs VI

Atoms Pub Date : 2024-02-27 DOI:10.3390/atoms12030013
Abid Husain, Haris Kunari, Tauheed Ahmad
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Abstract

Previously reported atomic data (spectral lines, wavelengths, energy levels, and transition probabilities) were collected and systematically analyzed for Cs VI. The present theoretical analysis was supported by extensive calculations made for Cs VI with a pseudo-relativistic Hartree–Fock (HFR) method together with the superposition of configuration interactions implemented in Cowan’s codes. In this work, all previously reported energy levels and their (allowed) transition assignments were confirmed. A critically evaluated set of optimized energy levels with their uncertainties, observed and Ritz wavelengths along with their uncertainties, and theoretical transition probabilities with their estimated uncertainties were presented in the compilation. In addition to this, we determined the radiative transition parameters for several forbidden lines within the ground configuration 5s25p2 of Cs VI.
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铯 VI 的能级和跃迁数据
收集并系统分析了 Cs VI 以前报告的原子数据(光谱线、波长、能级和跃迁概率)。利用伪相对论哈特里-福克(HFR)方法和 Cowan 代码中实施的构型相互作用叠加法对 Cs VI 进行了大量计算,为本理论分析提供了支持。在这项工作中,以前报告的所有能级及其(允许的)转变分配都得到了证实。经过严格评估的优化能级及其不确定性、观测波长和里兹波长及其不确定性,以及理论转变概率及其估计不确定性都在汇编中列出。此外,我们还确定了 Cs VI 地面构型 5s25p2 内几条禁用线的辐射转变参数。
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