A calcium aluminum rhenium sodalite with reducible rhenium in the sodalite cage

IF 1.8 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY MRS Communications Pub Date : 2024-04-12 DOI:10.1557/s43579-024-00550-7
Danrui Ni, Guangming Cheng, Lun Jin, Chen Yang, Nan Yao, Robert J. Cava
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Abstract

An unreported rhenium-based calcium aluminum sodalite (CARe sodalite) has been synthesized by a traditional solid-state method. The rhenium is located in the sodalite β-cage and can be reduced under 5% H2 forming gas without breaking the cage framework. Preliminary characterizations of the structural, optical, and magnetic properties are reported.

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钙铝铼钠盐石,钠盐石笼中含有可还原的铼
通过传统的固态方法合成了一种未报道过的铼基钙铝钠盐石(CARe sodalite)。铼位于钠铝石的 β 笼中,可在 5% 的 H2 生成气体中还原而不破坏笼的框架。报告对其结构、光学和磁学特性进行了初步表征。
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来源期刊
MRS Communications
MRS Communications MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
2.60
自引率
10.50%
发文量
166
审稿时长
>12 weeks
期刊介绍: MRS Communications is a full-color, high-impact journal focused on rapid publication of completed research with broad appeal to the materials community. MRS Communications offers a rapid but rigorous peer-review process and time to publication. Leveraging its access to the far-reaching technical expertise of MRS members and leading materials researchers from around the world, the journal boasts an experienced and highly respected board of principal editors and reviewers.
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