Influence of Elemental Sulfur on the Production of Materials for Road Surfacing

IF 0.4 Q4 ENGINEERING, CHEMICAL Coke and Chemistry Pub Date : 2024-05-13 DOI:10.3103/S1068364X24600076
N. T. Smagulova, Zh. K. Kairbekov, Zh. K. Aibassova
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Abstract

Coke plant tar is oxidized at 220°C in air current at 1.8 L/min for 4.5 h. In this process, elemental sulfur is added in quantities of 20, 30, and 40 wt %. With increase from 20 to 40 wt %, penetration declines from 55 to 38 mm; and the softening temperature (determined by the ring and rod method) declines from 52 to 45°C. The change in the physicomechanical properties of the mixture when adding 20, 30, and 40 wt % S is studied by X-ray phase analysis. With 30 wt % S, the reaction of sulfur with the aromatic rings forms 2-naphthanol-6-sulfonic acid (OHС10Н6SO3H).

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元素硫对公路铺面材料生产的影响
焦化厂焦油在 220°C、1.8 升/分钟的气流中氧化 4.5 小时。在此过程中,元素硫的添加量分别为 20、30 和 40 wt%。随着添加量从 20 wt % 增加到 40 wt %,渗透率从 55 mm 下降到 38 mm;软化温度(通过环棒法测定)从 52°C 下降到 45°C。通过 X 射线相分析法研究了添加 20、30 和 40 wt % S 时混合物物理机械性能的变化。当 S 的重量百分比为 30 时,硫与芳香环反应生成 2-萘酚-6-磺酸(OHС10Н6SO3H)。
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来源期刊
Coke and Chemistry
Coke and Chemistry ENGINEERING, CHEMICAL-
CiteScore
0.70
自引率
50.00%
发文量
36
期刊介绍: The journal publishes scientific developments and applications in the field of coal beneficiation and preparation for coking, coking processes, design of coking ovens and equipment, by-product recovery, automation of technological processes, ecology and economics. It also presents indispensable information on the scientific events devoted to thermal rectification, use of smokeless coal as an energy source, and manufacture of different liquid and solid chemical products.
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