Caterina Testa, Chiara M.A. Gangemi, Giuseppe Trusso Sfrazzetto, Martina Ricceri, Alessandro Giuffrida, Valentina Greco, Ambra Maria Cancelliere, Fausto Puntoriero, Andrea Pappalardo
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引用次数: 0
Abstract
A luminescent calix[5]arene with a covalently linked dansyl chromophore substituent
has been successfully used, both in solution and in the gas phase (ESI-MS), for the
recognition of biogenic amines that contain linear alkylammonium structural unit. Binding
constant values, determined by fluorescence spectroscopy, revealed a greater affinity for
cadaverine, spermidine, and L-lysine, in which the terminal ammonium group allows for
additional stabilizing interactions with the dansyl moiety.
the recognition of selected biogenic amines both in solution and in the gas phase (ESI-MS), and determining the relative binding constant values by fluorescence spectroscopy
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.