Performance Enhancement of Polyethersulfone-Based Ultrafiltration Membrane Decorated by Titanium Dioxide Nanoparticles for Dye Filtration

Ihal A. Abed, Basma I. Waisi
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Abstract

This study describes the modification of a polyethersulfone (PES)-based membrane by embedding titanium di - oxide ( TiO 2 ) nanoparticles. The prepared composite membranes are then characterized and applied for melechate green dye (MG) filtration from water to asses its filtering capabilities. The effect of TiO 2 contents on the morphology and filtration performance of the prepared composite membranes was evaluated by Fourier transform infrared (FTIR), scanning electron microscopy (SEM) and atomic force microscopy (AFM) analysis. The blended mem - branes displayed improved water permeability and dye rejection compared to the plain PES. The membrane char - acterization results showed that compared to the plain PES membrane, the porosity of pure membrane increased (from 15.1% to 34.7%) with increasing the percentage of the embedded TiO 2 . Then, the optical performance of the prepared membranes was examined in a cross-flow filtration system to separate MG dye from water. The filtration experiments showed that the composite PES/TiO 2 membrane of 1.5 wt.% TiO 2 has the best separation performance (permeate flux of 45 L/m 2 .hr and dye removal efficiency of 80%)
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二氧化钛纳米颗粒装饰的聚醚砜基超滤膜在染料过滤中的性能提升
本研究介绍了通过嵌入二氧化钛(TiO 2)纳米颗粒对基于聚醚砜(PES)的膜进行改性的方法。然后对制备的复合膜进行了表征,并将其用于过滤水中的甲基绿染料(MG),以评估其过滤能力。傅立叶变换红外(FTIR)、扫描电子显微镜(SEM)和原子力显微镜(AFM)分析评估了 TiO 2 含量对制备的复合膜的形态和过滤性能的影响。与普通聚醚砜相比,混合膜的透水性和染料阻隔性都有所提高。膜炭化结果表明,与普通 PES 膜相比,纯膜的孔隙率随着嵌入 TiO 2 的比例增加而增加(从 15.1% 增加到 34.7%)。然后,在横流过滤系统中检测了所制备膜的光学性能,以分离水中的 MG 染料。过滤实验表明,TiO 2 含量为 1.5 wt.% 的 PES/TiO 2 复合膜的分离性能最好(渗透通量为 45 L/m 2 .hr,染料去除率为 80%)。
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