Linking formulation feedstock to printability by robocasting: A case study of eco-friendly alumina pastes

IF 2.9 Q1 MATERIALS SCIENCE, CERAMICS Open Ceramics Pub Date : 2024-06-01 DOI:10.1016/j.oceram.2024.100606
Delphine Gourdonnaud , Julie Bourret , Vincent Pateloup , Lisa Giardi , Luc Picton , Vincent Chaleix , Thierry Chartier , Benoit Naït-Ali , Marguerite Bienia , Pierre-Marie Geffroy
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Abstract

Robocasting stands as a pertinent additive manufacturing technique for producing intricate ceramic parts. Amidst stricter environmental regulations, the adoption of natural additives becomes imperative. This study investigates the influence of plant-based additives on the rheology and printability of eco-friendly pastes.

Various 50 vol%-alumina pastes were formulated using natural binders, plasticizers and dispersants (e.g., lignosulfonate, polysaccharides, glycerol) and then assessed through oscillation and flow rheological analyses. Paste viscosity and rigidity often deviated from printability maps reported in the literature, showing the complexity of defining universal printability criteria. A comprehensive investigation was conducted on the water retention capabilities of additives, liquid phase migration and paste drying kinetics.

This paper highlights the critical importance of constraining liquid phase migration within eco-friendly ceramic pastes and the crucial role of polymer chain reorientation under shear. Consequently, this research lays diversifying formulations, offering sustainable solutions for industrial ceramic applications.

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将配方原料与机器人浇注的可印刷性联系起来:生态友好型氧化铝浆料的案例研究
机器人铸造是生产复杂陶瓷部件的一种相关添加剂制造技术。在环保法规日益严格的情况下,采用天然添加剂势在必行。本研究调查了植物基添加剂对环保型浆料的流变性和可印刷性的影响。研究人员使用天然粘合剂、增塑剂和分散剂(如木质素磺酸盐、多糖、甘油)配制了各种 50 Vol% 氧化铝浆料,然后通过振荡和流动流变分析进行了评估。浆糊的粘度和刚度往往偏离文献中报道的印刷适性图,这显示了定义通用印刷适性标准的复杂性。本文强调了限制环保陶瓷浆料中液相迁移的重要性,以及聚合物链在剪切力作用下重新定向的关键作用。因此,这项研究提出了多样化的配方,为工业陶瓷应用提供了可持续的解决方案。
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来源期刊
Open Ceramics
Open Ceramics Materials Science-Materials Chemistry
CiteScore
4.20
自引率
0.00%
发文量
102
审稿时长
67 days
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