Carbonylative transformation of aryl halides and strong bonds via cheap metal catalysts and sustainable technologies

Maolin Yang , Yukun Liu , Xin Qi , Yanhua Zhao , Xiao-Feng Wu
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Abstract

The development of catalytic carbonylation reactions has increased considerably. Although many reviews/chapters/books on carbonylation reactions have been published, summaries on cheap metal-catalyzed catalytic carbonylation reactions of aryl halides and other chemical bonds with high dissociation energy C–Y (Y ​= ​O, N, H) are still very rare. Focusing on green and sustainable chemistry, this review summarizes and discusses the achievements on carbonylative transformations of aryl halides (C(sp2)–X) and strong bonds C–Y (Y ​= ​O, N, H) based on non-expensive metal catalysts (Co, Mn, Mo, Ni, Fe, Cu), photochemical and electrochemical systems developed in recent decades.

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通过廉价金属催化剂和可持续技术实现芳基卤化物和强键的羰基转化
催化羰基化反应的发展已大大增加。虽然已经发表了很多关于羰基化反应的综述/章节/书籍,但关于廉价金属催化芳基卤化物催化羰基化反应和其他具有高离解能的化学键C-Y (Y = O, N, H)的综述仍然很少。以绿色化学和可持续化学为重点,综述和讨论了近几十年来基于非昂贵金属催化剂(Co, Mn, Mo, Ni, Fe, Cu)和光化学和电化学体系的芳基卤化物(C(sp2) -X)和强键C - Y (Y = O, N, H)羰基化转化的研究进展。
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