{"title":"Investigation of the efficacy of <i>Alhagi maurorum</i> plant powder for Janus Green B dye removal from wastewater.","authors":"Saeideh Kalantari, Mahdi Tazeh","doi":"10.1080/15226514.2024.2354415","DOIUrl":null,"url":null,"abstract":"<p><p>The growth of industrial activities, has led to a significant increase in the influx of color pollutants into the environment. Phytoremediation can play a crucial role in enhancing wastewater quality. Accordingly, this study sought to evaluate the effectiveness of <i>Alhagi maurorum</i> plant powder in removing Janus Green B (JGB) dye from aqueous solutions. The adsorbent's properties were characterized through Fourier-transform infrared spectroscopy. The study examined various parameters, including initial dye concentration (20-110 mg/L), adsorbent dosage (0.002-0.02 g), solution pH (2-10), and contact time (5-50 min). The experiments revealed that the maximum dye removal efficiency, 99.51%, was achieved under optimal conditions: pH 7, a contact time of 20 min, an adsorbent dosage of 0.01 g, and an initial dye concentration of 90 mg/L. The adsorption of JGB onto the adsorbent followed the Langmuir isotherm model, with a maximum adsorption capacity of 90.909 mg/g. The kinetic results supported a pseudo-second-order model for the adsorption process, with an <i>R</i><sup>2</sup> value of 0.9999. The calculated Gibbs free energy changes (Δ<i>G</i>°) at temperatures of 288, 298, 308, 318, and 328 K were found to be -5354.28, -5993.61, -6439.66, -7026.51, and -7932.05 kJ/mol, respectively, indicating the spontaneity of the adsorption process.</p>","PeriodicalId":3,"journal":{"name":"ACS Applied Electronic Materials","volume":null,"pages":null},"PeriodicalIF":4.3000,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Electronic Materials","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.1080/15226514.2024.2354415","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/5/22 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0
Abstract
The growth of industrial activities, has led to a significant increase in the influx of color pollutants into the environment. Phytoremediation can play a crucial role in enhancing wastewater quality. Accordingly, this study sought to evaluate the effectiveness of Alhagi maurorum plant powder in removing Janus Green B (JGB) dye from aqueous solutions. The adsorbent's properties were characterized through Fourier-transform infrared spectroscopy. The study examined various parameters, including initial dye concentration (20-110 mg/L), adsorbent dosage (0.002-0.02 g), solution pH (2-10), and contact time (5-50 min). The experiments revealed that the maximum dye removal efficiency, 99.51%, was achieved under optimal conditions: pH 7, a contact time of 20 min, an adsorbent dosage of 0.01 g, and an initial dye concentration of 90 mg/L. The adsorption of JGB onto the adsorbent followed the Langmuir isotherm model, with a maximum adsorption capacity of 90.909 mg/g. The kinetic results supported a pseudo-second-order model for the adsorption process, with an R2 value of 0.9999. The calculated Gibbs free energy changes (ΔG°) at temperatures of 288, 298, 308, 318, and 328 K were found to be -5354.28, -5993.61, -6439.66, -7026.51, and -7932.05 kJ/mol, respectively, indicating the spontaneity of the adsorption process.