{"title":"Cobalt -supported [Aemim]Br ionic liquid for the catalytic suzuki-miyaura coupling reactions","authors":"Karthikeyan Parasuraman , Uthayanila Selvarasu , Venkatesan Kasi , Ramasamy Shanmugapriya","doi":"10.1016/j.cinorg.2024.100056","DOIUrl":null,"url":null,"abstract":"<div><p>This communication describes a highly recyclable, ecologically friendly, ionic liquid catalyst supported by cobalt that is active in the Suzuki-Miyaura reaction at 70 °C. To be more precise, the procedure is initiated with a special form of the ecologically safe solvent 3-(2-aminoethyl)-1-methyl-1H-imidazole-3-ium bromide [Aemim]Br. A few benefits of the coupling process include its simplicity of use, broad range of substrate compatibility with high yields, environmental friendliness, high reaction rate, low catalyst loading (0.001 mol%), and recyclability (up to 7 cycles).</p></div>","PeriodicalId":100233,"journal":{"name":"Chemistry of Inorganic Materials","volume":"3 ","pages":"Article 100056"},"PeriodicalIF":0.0000,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949746924000247/pdfft?md5=1e78e2a9f89ce8a11ecb1a16ea2de0a9&pid=1-s2.0-S2949746924000247-main.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry of Inorganic Materials","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2949746924000247","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/5/23 0:00:00","PubModel":"Epub","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract
This communication describes a highly recyclable, ecologically friendly, ionic liquid catalyst supported by cobalt that is active in the Suzuki-Miyaura reaction at 70 °C. To be more precise, the procedure is initiated with a special form of the ecologically safe solvent 3-(2-aminoethyl)-1-methyl-1H-imidazole-3-ium bromide [Aemim]Br. A few benefits of the coupling process include its simplicity of use, broad range of substrate compatibility with high yields, environmental friendliness, high reaction rate, low catalyst loading (0.001 mol%), and recyclability (up to 7 cycles).
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