A. I. Kazakov, D. B. Lempert, A. V. Nabatova, E. L. Ignatieva, D. V. Dashko, V. V. Raznoschikov, L. S. Yanovskiy
{"title":"Kinetics of the Thermal Decomposition of Methyl Derivatives of 7H-Difurazanofuxanoazepine and 7H-Tryfurasanoazepine","authors":"A. I. Kazakov, D. B. Lempert, A. V. Nabatova, E. L. Ignatieva, D. V. Dashko, V. V. Raznoschikov, L. S. Yanovskiy","doi":"10.1134/S1990793124020210","DOIUrl":null,"url":null,"abstract":"<p>The thermal stability of N-methyl derivatives of 7<i>H</i>-difurazanofuroxanoazepine and 7<i>H</i>-trifurazanoazepine in the nonisothermal and isothermal modes is studied. The formal-kinetic laws of the decomposition and temperature dependencies of the reaction rate constants are determined. The thermal stability of methyl, propargyl, cyanomethyl, allyl, and amine derivatives of azepines is compared.</p>","PeriodicalId":768,"journal":{"name":"Russian Journal of Physical Chemistry B","volume":null,"pages":null},"PeriodicalIF":1.4000,"publicationDate":"2024-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry B","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1990793124020210","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The thermal stability of N-methyl derivatives of 7H-difurazanofuroxanoazepine and 7H-trifurazanoazepine in the nonisothermal and isothermal modes is studied. The formal-kinetic laws of the decomposition and temperature dependencies of the reaction rate constants are determined. The thermal stability of methyl, propargyl, cyanomethyl, allyl, and amine derivatives of azepines is compared.
期刊介绍：
Russian Journal of Physical Chemistry B: Focus on Physics is a journal that publishes studies in the following areas: elementary physical and chemical processes; structure of chemical compounds, reactivity, effect of external field and environment on chemical transformations; molecular dynamics and molecular organization; dynamics and kinetics of photoand radiation-induced processes; mechanism of chemical reactions in gas and condensed phases and at interfaces; chain and thermal processes of ignition, combustion and detonation in gases, two-phase and condensed systems; shock waves; new physical methods of examining chemical reactions; and biological processes in chemical physics.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
