N. N. Shevchenko, O. D. Iakobson, E. M. Ivan’kova, A. V. Sel’kin
{"title":"Formation of Composite Polymer Photonic Crystals and Study of Their Properties by Optical Spectroscopy Methods","authors":"N. N. Shevchenko, O. D. Iakobson, E. M. Ivan’kova, A. V. Sel’kin","doi":"10.1134/S1560090424600335","DOIUrl":null,"url":null,"abstract":"<p>Monodisperse polymer particles of the core–shell type were produced using sequential emulsion and seed emulsion polymerization methods. The structure of the surface layer of the particles was studied using scanning electron microscopy. It has been established that sequential emulsion polymerization makes it possible to obtain particles with the lowest dispersity values of their diameter. The introduction of methyl methacrylate both at the stage of core synthesis and during the formation of the shell leads to the formation of spherical particles with a smooth surface layer. Based on such particles, films with pronounced properties of photonic crystals were obtained, and their Bragg reflection spectra in polarized light were studied.</p>","PeriodicalId":739,"journal":{"name":"Polymer Science, Series B","volume":"66 1","pages":"79 - 88"},"PeriodicalIF":1.0000,"publicationDate":"2024-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series B","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S1560090424600335","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
Monodisperse polymer particles of the core–shell type were produced using sequential emulsion and seed emulsion polymerization methods. The structure of the surface layer of the particles was studied using scanning electron microscopy. It has been established that sequential emulsion polymerization makes it possible to obtain particles with the lowest dispersity values of their diameter. The introduction of methyl methacrylate both at the stage of core synthesis and during the formation of the shell leads to the formation of spherical particles with a smooth surface layer. Based on such particles, films with pronounced properties of photonic crystals were obtained, and their Bragg reflection spectra in polarized light were studied.
期刊介绍:
Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed