Dr. Viktor Bliksted Roug Pedersen, Prof. Dr. Ramesh Jasti, Prof. Dr. Mogens Brøndsted Nielsen
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引用次数: 0
Abstract
Two regioisomeric extended tetrathiafulvalenes (TTFs) incorporating diindeno-fused corannulene spacers were synthesized from suitable dione precursors using Horner-Wadsworth-Emmons olefination reactions. Both compounds are strong chromophores with a longest-wavelength absorption that exhibited some degree of charge-transfer character as inferred from solvatochromic behaviors and frontier orbital calculations. The compounds underwent two reversible one-electron oxidations and a quasi-reversible third oxidation during cyclic voltammetry conditions. The mono- and dications had characteristic NIR absorptions and both were EPR active. The dications with potential diradicaloid characters underwent reactions when generated in bulk.
ChemPhotoChemChemistry-Physical and Theoretical Chemistry
CiteScore
5.80
自引率
5.40%
发文量
165
期刊介绍：
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