{"title":"Synthesis and Properties of 1,3-Dithiole[6]dendralene Analogs with Two Thiophene Spacers Inserted","authors":"Tomoya Misaki, Masataka Nishiwaki, Toshiki Ito, Masafumi Ueda, Masahiro Fujisaki, Aya Yoshimura, Takashi Shirahata, Minoru Hayashi, Yohji Misaki","doi":"10.1093/chemle/upae104","DOIUrl":null,"url":null,"abstract":"Derivatives of a 1,3-dithiole[6]dendralene analog with two thiophene spacers inserted (2) have been successfully synthesized. Cyclic voltammetry and spectroelectrochemistry revealed that their redox behavior, based on the distribution of the positive charges, differed depending on the position and the electronic effect of substituents on the 1,3-dithiole rings.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1093/chemle/upae104","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Derivatives of a 1,3-dithiole[6]dendralene analog with two thiophene spacers inserted (2) have been successfully synthesized. Cyclic voltammetry and spectroelectrochemistry revealed that their redox behavior, based on the distribution of the positive charges, differed depending on the position and the electronic effect of substituents on the 1,3-dithiole rings.
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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