A. S. Avksentiev, V. Sh. Saberov, G. F. Rayenko, A. B. Ryabitsky, E. V. Polunkin, S. M. Pleskun, N. I. Korotkikh
{"title":"Catalysis of the Transesterification Reaction of Alkyl Benzoates and Vegetable Oils by Carbonates, Carbene, and Anionite","authors":"A. S. Avksentiev, V. Sh. Saberov, G. F. Rayenko, A. B. Ryabitsky, E. V. Polunkin, S. M. Pleskun, N. I. Korotkikh","doi":"10.1007/s11237-024-09802-y","DOIUrl":null,"url":null,"abstract":"<p>The catalytic effect of alkali metal carbonates, in situ generated carbene, and anionite in the transesterification reaction of alkyl benzoates with methanol, ethanol, benzyl alcohol, and cyclohexanol, as well as vegetable oils with methanol and ethanol was studied. Catalytic reactions with methanol occur at room temperature with yields close to quantitative. The reactions of the vegetable oils in the presence of potassium carbonate with small amounts of methanol or ethanol (3.2 eq) at room temperature lead to high yields of biodiesel fuel and are suitable for industrial use.</p>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical and Experimental Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11237-024-09802-y","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The catalytic effect of alkali metal carbonates, in situ generated carbene, and anionite in the transesterification reaction of alkyl benzoates with methanol, ethanol, benzyl alcohol, and cyclohexanol, as well as vegetable oils with methanol and ethanol was studied. Catalytic reactions with methanol occur at room temperature with yields close to quantitative. The reactions of the vegetable oils in the presence of potassium carbonate with small amounts of methanol or ethanol (3.2 eq) at room temperature lead to high yields of biodiesel fuel and are suitable for industrial use.
期刊介绍：
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
