Fast and eco-friendly synthesis of carbon dots from pinecone for highly effective detection of 2,4,6-trinitrophenol in environmental samples.

Abstract

2,4,6-Trinitrophenol (TNP) has high explosive risks and biological toxicity, and there has been considerable concern over the determination of TNP. In the present work, fluorescent carbon dots (CDs) stemmed from a green carbon source of pinecone by the facile hydrothermal approach. A novel environment- friendly fluorescent probe was developed to efficiently detect TNP by using the obtained CDs with remarkable fluorescence stability. The fluorescent CDs exhibited obvious excitation dependence with the highest peaks for excitation and emission occurring at 321 and 411 nm, respectively. The fluorescence intensity is significantly reduced by TNP owing to the inner filter effect with the CDs. The probe exhibited good linearity with TNP concentrations in the range of 0.025-20 μg mL^-1, and the limit of detection was as low as 8.5 ng mL^-1. Additionally, the probe proved successful in sensing TNP quantitatively in actual environmental samples with satisfied recoveries of 95.6-99.6%. The developed fluorescent probe offered an environment-friendly, efficient, rapid, and reliable platform for detecting trace TNP in the environmental field.Highlights Novel carbon dots were synthesised from green precursors of pineal powder.The highly effective quenching process was put down to the inner filter effect.The as-constructed fluorescent probe was successfully utilised for sensing 2,4,6-trinitrophenol in environmental samples.The proposed method was simple, rapid, efficient, economical, and eco-friendly.