Jorge Reyna-Alvarado, Oscar A. López-Galán, Jorge Trimmer, Oscar Recalde-Benitez, Leopoldo Molina, Albina Gutiérrez-Martínez, Raúl Pérez-Hernández, Manuel Ramos
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引用次数: 0
Abstract
This study presents the synthesis and characterization of the Co supported on CeO2 nanorods (NR) catalyst to investigate catalytic performance towards efficient hydrogen production. The catalyst was characterized by transmission electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction. Temperature-programmed reduction measurements showed that the Co/CeO2-NR active phase was reduced below 500°C. Adding Co to CeO2-NR enhances the basicity of the raw CeO2-NR and greatly improves the conversion to 70% for CO2 and 55% for CH4. In addition, density functional theory calculations using Halgren–Lipscomb indicate electron donation from Co to CeO2-NR promotes feasible breaking of C–H bonds.
期刊介绍：
MRS Communications is a full-color, high-impact journal focused on rapid publication of completed research with broad appeal to the materials community. MRS Communications offers a rapid but rigorous peer-review process and time to publication. Leveraging its access to the far-reaching technical expertise of MRS members and leading materials researchers from around the world, the journal boasts an experienced and highly respected board of principal editors and reviewers.
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