{"title":"Boryl radicals facilitate C(sp2)–C(sp3) cross-coupling reactions","authors":"Jesus Rodrigalvarez, Ruben Martin","doi":"10.1038/s44160-024-00586-6","DOIUrl":null,"url":null,"abstract":"Amine–borane adducts activate alkyl halides via halogen-atom transfer through boryl radical intermediates, enabling the formation of C(sp2)–C(sp3) bonds using either organometallic reagents or organic halides.","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":"3 10","pages":"1188-1189"},"PeriodicalIF":0.0000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nature synthesis","FirstCategoryId":"1085","ListUrlMain":"https://www.nature.com/articles/s44160-024-00586-6","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"0","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Amine–borane adducts activate alkyl halides via halogen-atom transfer through boryl radical intermediates, enabling the formation of C(sp2)–C(sp3) bonds using either organometallic reagents or organic halides.
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