{"title":"Fabrication of a new nickel iron-titanate perovskite composite with enhanced visible light photocatalytic activity","authors":"Byung-Geon Park","doi":"10.1007/s11243-024-00595-6","DOIUrl":null,"url":null,"abstract":"<p>In this study, a nickel iron-titanate (NiFeTiO<sub>3</sub>) perovskite composite was prepared newly and its photocatalytic activity was evaluated under visible light irradiation. The composite material was prepared by a synthetic method combining the sol–gel method and the solvothermal method. The physicochemical and optical properties of the prepared NiFeTiO<sub>3</sub> perovskites were investigated. In this study, a newly prepared NiFeTiO<sub>3</sub> perovskite composite was evaluated for its photocatalytic activity under visible light irradiation. The composite material was synthesized using a combination of the sol–gel method and the solvothermal method. The physicochemical and optical properties of the prepared NiFeTiO<sub>3</sub> perovskites were investigated. The perovskite composites with the NiFeTiO<sub>3</sub> structure had excellent absorption ability for visible light above 800 nm. Its bandgap energy was found to be approximately 1.8 eV. The photocatalytic activity of the NiFeTiO<sub>3</sub> composite was evaluated under visible light irradiation. The NiFeTiO<sub>3</sub> had superior visible light absorption ability compared to NiTiO<sub>3</sub>. It had excellent decomposition performance for methylene blue and formaldehyde. In addition, the photocatalytic activity for sterilizing pathogenic bacteria was much higher than that of NiTiO<sub>3</sub> perovskite. In the water splitting by solar energy, the NiFeTiO<sub>3</sub> catalysts produced hydrogen through a photocatalytic decomposition reaction. The NiFeTiO<sub>3</sub> composite was considered a perovskite composite with significantly improved photocatalytic function due to its high sensitivity to visible light.</p>","PeriodicalId":803,"journal":{"name":"Transition Metal Chemistry","volume":"27 1","pages":""},"PeriodicalIF":1.6000,"publicationDate":"2024-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transition Metal Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s11243-024-00595-6","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
In this study, a nickel iron-titanate (NiFeTiO3) perovskite composite was prepared newly and its photocatalytic activity was evaluated under visible light irradiation. The composite material was prepared by a synthetic method combining the sol–gel method and the solvothermal method. The physicochemical and optical properties of the prepared NiFeTiO3 perovskites were investigated. In this study, a newly prepared NiFeTiO3 perovskite composite was evaluated for its photocatalytic activity under visible light irradiation. The composite material was synthesized using a combination of the sol–gel method and the solvothermal method. The physicochemical and optical properties of the prepared NiFeTiO3 perovskites were investigated. The perovskite composites with the NiFeTiO3 structure had excellent absorption ability for visible light above 800 nm. Its bandgap energy was found to be approximately 1.8 eV. The photocatalytic activity of the NiFeTiO3 composite was evaluated under visible light irradiation. The NiFeTiO3 had superior visible light absorption ability compared to NiTiO3. It had excellent decomposition performance for methylene blue and formaldehyde. In addition, the photocatalytic activity for sterilizing pathogenic bacteria was much higher than that of NiTiO3 perovskite. In the water splitting by solar energy, the NiFeTiO3 catalysts produced hydrogen through a photocatalytic decomposition reaction. The NiFeTiO3 composite was considered a perovskite composite with significantly improved photocatalytic function due to its high sensitivity to visible light.
期刊介绍:
Transition Metal Chemistry is an international journal designed to deal with all aspects of the subject embodied in the title: the preparation of transition metal-based molecular compounds of all kinds (including complexes of the Group 12 elements), their structural, physical, kinetic, catalytic and biological properties, their use in chemical synthesis as well as their application in the widest context, their role in naturally occurring systems etc.
Manuscripts submitted to the journal should be of broad appeal to the readership and for this reason, papers which are confined to more specialised studies such as the measurement of solution phase equilibria or thermal decomposition studies, or papers which include extensive material on f-block elements, or papers dealing with non-molecular materials, will not normally be considered for publication. Work describing new ligands or coordination geometries must provide sufficient evidence for the confident assignment of structural formulae; this will usually take the form of one or more X-ray crystal structures.