Molecular engineering of coumarins for enhanced two-photon absorption property

IF 1.4 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Chemistry Letters Pub Date : 2024-07-09 DOI:10.1093/chemle/upae131
Fan Zhang, Yong-Hsin Wang, Cheng-Lin Wu, Tzu-Chau Lin, Manabu Abe
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Abstract

A series of coumarin-based quadrupolar and octupolar derivatives containing electron-donating substituents (carbazole or diphenylamine groups) were synthesized. Their photophysical properties were explored in different organic solvents (toluene, dichloromethane, and dimethyl sulfoxide). Each donor group was connected via cyclic stilbene based on coumarin, resulting in compounds with large two-photon absorption cross-sections.
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增强双光子吸收特性的香豆素分子工程学
研究人员合成了一系列香豆素类四极和八极衍生物,这些衍生物含有电子捐赠取代基(咔唑或二苯胺基团)。研究人员在不同的有机溶剂(甲苯、二氯甲烷和二甲亚砜)中探索了它们的光物理特性。每个供体基团都通过基于香豆素的环状链烯连接,从而产生了具有较大双光子吸收截面的化合物。
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来源期刊
Chemistry Letters
Chemistry Letters 化学-化学综合
CiteScore
3.00
自引率
6.20%
发文量
260
审稿时长
1.2 months
期刊介绍: Chemistry Letters covers the following topics: -Organic Chemistry- Physical Chemistry- Inorganic Chemistry- Analytical Chemistry- Materials Chemistry- Polymer Chemistry- Supramolecular Chemistry- Organometallic Chemistry- Coordination Chemistry- Biomolecular Chemistry- Natural Products and Medicinal Chemistry- Electrochemistry
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