Isotopic shift analysis of GdO by LAMIS

IF 3.2 2区 化学 Q1 SPECTROSCOPY Spectrochimica Acta Part B: Atomic Spectroscopy Pub Date : 2024-07-14 DOI:10.1016/j.sab.2024.106993
M. Gaft , L. Nagli , J. Fernandes , V. Gardette , Y. Raichlin , V. Motto-Ros
{"title":"Isotopic shift analysis of GdO by LAMIS","authors":"M. Gaft ,&nbsp;L. Nagli ,&nbsp;J. Fernandes ,&nbsp;V. Gardette ,&nbsp;Y. Raichlin ,&nbsp;V. Motto-Ros","doi":"10.1016/j.sab.2024.106993","DOIUrl":null,"url":null,"abstract":"<div><p>LAMIS is a known technique for isotopic shift analysis of light elements, such as B, C, etc. Its application for heavy molecules has been studied less. We proved that vibrational and rotational transitions A(1–0), A(1–2), and A(2–1) of GdO in Laser-Induced Plasma exhibit apparent differences between natural GdO, <sup>156</sup>GdO, and <sup>158</sup>GdO emissions. The absolute values are in the 0.4–0.5 cm<sup>−1</sup> range. Besides its adequate spectral resolution, the Demon HR Double Echelle Monochromator proved its sensitivity for isotopic analysis of Rare Earth Elements.</p></div>","PeriodicalId":21890,"journal":{"name":"Spectrochimica Acta Part B: Atomic Spectroscopy","volume":"218 ","pages":"Article 106993"},"PeriodicalIF":3.2000,"publicationDate":"2024-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica Acta Part B: Atomic Spectroscopy","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S058485472400137X","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"SPECTROSCOPY","Score":null,"Total":0}
引用次数: 0

Abstract

LAMIS is a known technique for isotopic shift analysis of light elements, such as B, C, etc. Its application for heavy molecules has been studied less. We proved that vibrational and rotational transitions A(1–0), A(1–2), and A(2–1) of GdO in Laser-Induced Plasma exhibit apparent differences between natural GdO, 156GdO, and 158GdO emissions. The absolute values are in the 0.4–0.5 cm−1 range. Besides its adequate spectral resolution, the Demon HR Double Echelle Monochromator proved its sensitivity for isotopic analysis of Rare Earth Elements.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
利用 LAMIS 对氧化钆进行同位素位移分析
LAMIS 是一种已知的轻元素(如 B、C 等)同位素偏移分析技术。对其在重分子中的应用研究较少。我们证明,在激光诱导等离子体中,氧化钆的振动和旋转跃迁 A(1-0)、A(1-2) 和 A(2-1) 在天然氧化钆、156氧化钆和 158氧化钆的发射中表现出明显的差异。绝对值在 0.4-0.5 cm-1 范围内。除了具有足够的光谱分辨率之外,Demon HR 双梯度单色仪还证明了其在稀土元素同位素分析方面的灵敏度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
CiteScore
6.10
自引率
12.10%
发文量
173
审稿时长
81 days
期刊介绍: Spectrochimica Acta Part B: Atomic Spectroscopy, is intended for the rapid publication of both original work and reviews in the following fields: Atomic Emission (AES), Atomic Absorption (AAS) and Atomic Fluorescence (AFS) spectroscopy; Mass Spectrometry (MS) for inorganic analysis covering Spark Source (SS-MS), Inductively Coupled Plasma (ICP-MS), Glow Discharge (GD-MS), and Secondary Ion Mass Spectrometry (SIMS). Laser induced atomic spectroscopy for inorganic analysis, including non-linear optical laser spectroscopy, covering Laser Enhanced Ionization (LEI), Laser Induced Fluorescence (LIF), Resonance Ionization Spectroscopy (RIS) and Resonance Ionization Mass Spectrometry (RIMS); Laser Induced Breakdown Spectroscopy (LIBS); Cavity Ringdown Spectroscopy (CRDS), Laser Ablation Inductively Coupled Plasma Atomic Emission Spectroscopy (LA-ICP-AES) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS). X-ray spectrometry, X-ray Optics and Microanalysis, including X-ray fluorescence spectrometry (XRF) and related techniques, in particular Total-reflection X-ray Fluorescence Spectrometry (TXRF), and Synchrotron Radiation-excited Total reflection XRF (SR-TXRF). Manuscripts dealing with (i) fundamentals, (ii) methodology development, (iii)instrumentation, and (iv) applications, can be submitted for publication.
期刊最新文献
Assessment of acupuncture's effectiveness in treating gulf war illness using laser induced breakdown spectroscopy and inductively coupled plasma mass spectrometry Characterization of the distribution of mineral elements in chromium-stressed rice (Oryza sativa L.) leaves based on laser-induced breakdown spectroscopy and data augmentation Rapid determination of 90Sr in seawater using a novel porous crown-based resin and tandem quadrupole ICP-MS/MS in cool plasma and O2-He mode Consideration of spectral interference in total reflection X-ray fluorescence analysis using a limited number of calibration samples: Case study of ocean polymetallic nodules Signal enhancement with double-pulse LIBS on biological samples and better discrimination of tissues through machine learning algorithms
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1