{"title":"Dicarbonyl-1κ2C-μ-chlorido-2:3κ2Cl:Cl-pentachlorido-2κ2Cl,3κ3Cl-[1(η6)-toluene]digallium(III)ruthenium(I)(Ru—Ga)","authors":"Danielle Smith , George N. Harakas","doi":"10.1107/S2414314624006576","DOIUrl":null,"url":null,"abstract":"<div><p>The title compound is a ruthenium–gallium metal cluster. The ruthenium and gallium have a direct metal–metal bond with a length of 2.4575 (2) Å.</p></div><div><p>The title compound, [RuGa<sub>2</sub>Cl<sub>6</sub>(C<sub>7</sub>H<sub>8</sub>)(CO)<sub>2</sub>] or [(CO)<sub>2</sub>(GaCl<sub>2</sub>)(η<sup>6</sup>-toluene)Ru]<sup>+</sup>[GaCl<sub>4</sub>]<sup>−</sup>, was isolated from the reaction of Ga<sub>2</sub>Cl<sub>4</sub> with diphenylsilanediol in toluene, followed by the addition of Ru<sub>3</sub>(CO)<sub>12</sub>. The compound contains a ruthenium–gallium metal–metal bond with a length of 2.4575 (2) Å.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (242KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></p></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 7","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624000646","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract
The title compound is a ruthenium–gallium metal cluster. The ruthenium and gallium have a direct metal–metal bond with a length of 2.4575 (2) Å.
The title compound, [RuGa2Cl6(C7H8)(CO)2] or [(CO)2(GaCl2)(η6-toluene)Ru]+[GaCl4]−, was isolated from the reaction of Ga2Cl4 with diphenylsilanediol in toluene, followed by the addition of Ru3(CO)12. The compound contains a ruthenium–gallium metal–metal bond with a length of 2.4575 (2) Å.
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