Progress of CO2 fixation using cycloaddition reaction

Xing Chen , Ye Liu , Guoqiang Wang , Lei Zhang , Yubo Kuang , Haohan Tao , Xiaoqian Xiang , Guangran Di , Xiaojing Yin , Kaixin Wang , Qianqian Cai , Xiaojun Lv
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Abstract

Carbon dioxide, a significant greenhouse gas component, has been impacting the global climate. Photocatalytic CO2 reduction is a cost-effective and eco-friendly approach. Photocatalytic CO2 can combine with epoxides to produce cyclic carbonates, garnering considerable attention due to its full atom utilization and alignment with green chemistry principles. This review assesses the current state of research on photocatalytic CO2 cycloaddition with epoxides, examining factors influencing efficiency through pathways and enhancement methods like light absorption, separation and transfer of photogenerated charges, active site reaction, coupling reaction, and reaction device.

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利用环化反应固定二氧化碳的进展
二氧化碳是重要的温室气体成分,一直影响着全球气候。光催化还原二氧化碳是一种具有成本效益且环保的方法。光催化二氧化碳可与环氧化物结合生成环状碳酸盐,因其原子的充分利用和符合绿色化学原则而备受关注。本综述评估了光催化二氧化碳与环氧化物环加成的研究现状,通过光吸收、光生电荷的分离和转移、活性位点反应、偶联反应和反应装置等途径和增强方法,探讨了影响效率的因素。
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Editorial Board Advance of self-cleaning separation membranes for oil-containing wastewater treatment Modified Titanium dioxide-based photocatalysts for water treatment: Mini review Progress of CO2 fixation using cycloaddition reaction The application of diatomic catalysts in advanced oxidation Fenton-like water treatment technology:A mini review
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