Classification and summary of photocatalytic chemical reactions driven by triplet‐triplet annihilation upconversion

IF 3 4区 化学 Q3 CHEMISTRY, PHYSICAL ChemPhotoChem Pub Date : 2024-07-27 DOI:10.1002/cptc.202400184
Wen Yao, Xiaojuan Song, Lin Xue, Shanshan Liu, Linglong Tang, Heyuan Liu, Yanli Chen, Xiyou Li
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Abstract

Triplet‐triplet annihilation upconversion (TTA‐UC) technology could convert low‐energy light into high‐energy light, and it is a very promising one of the upconversion technologies due to its non‐coherent excitation light, low required excitation optical power density and sensitizer/annihilator flexible adjustability. The application of TTA‐UC into photocatalysis could not only broaden the range of solar energy spectrum utilization, but also bring mild reaction conditions and higher product yields via avoiding the side reaction. However, the detailed catalytic mechanism of TTA‐UC is unclear. Therefore, in this review, we summarized and classified TTA‐UC photocatalytic chemical reactions in terms of mechanism.
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三重-三重湮灭上转换驱动的光催化化学反应的分类和总结
三重-三重湮灭上转换(TTA-UC)技术可将低能光转换为高能光,具有非相干激发光、所需激发光功率密度低、敏化剂/湮灭剂可灵活调节等特点,是一种非常有前景的上转换技术。将 TTA-UC 应用于光催化,不仅能拓宽太阳能光谱的利用范围,还能避免副反应,带来温和的反应条件和更高的产物产率。然而,TTA-UC 的详细催化机理尚不清楚。因此,在本综述中,我们从机理方面对 TTA-UC 光催化化学反应进行了总结和分类。
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来源期刊
ChemPhotoChem
ChemPhotoChem Chemistry-Physical and Theoretical Chemistry
CiteScore
5.80
自引率
5.40%
发文量
165
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