Gamma irradiation effects on Eu(III) uptake by HDEHP-functionalized support materials

IF 1.5 3区 化学 Q3 CHEMISTRY, ANALYTICAL Journal of Radioanalytical and Nuclear Chemistry Pub Date : 2024-07-25 DOI:10.1007/s10967-024-09655-8
Ridhita B. Borhan, Diana Thompson, Erin R. Bertelsen
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Abstract

Four chromatographic supports were functionalized with bis-(2-ethylhexyl) phosphoric acid (HDEHP) and examined for radiation stability when used for f-element separations after exposure to high levels of ionizing gamma radiation. Changes in Eu(III) partitioning were evaluated and compared to an analogous solvent extraction system using HDEHP in n-dodecane. The solvent extraction system showed an increase in Eu(III) uptake with increasing γ irradiation dose to the solvent in the presence of nitric acid. The Eu(III) distribution profiles indicate that the functionalized chromatographic support materials are less affected by γ irradiation, when exposed in a radiation environment of up to 2.5 MGy in the presence of nitric acid.

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伽马辐照对 HDEHP 功能化支撑材料吸收 Eu(III) 的影响
用双(2-乙基己基)磷酸(HDEHP)对四种色谱支持物进行了官能化,并考察了它们在暴露于高水平电离伽马辐射后用于 f 元素分离时的辐射稳定性。评估了 Eu(III)分配的变化,并与在正十二烷中使用 HDEHP 的类似溶剂萃取系统进行了比较。溶剂萃取系统显示,在硝酸存在的情况下,随着对溶剂的γ辐照剂量的增加,Eu(III)的吸收量也在增加。Eu(III)的分布曲线表明,在硝酸存在的情况下,功能化色谱支持材料在高达 2.5 MGy 的辐照环境中受 γ 辐照的影响较小。
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来源期刊
CiteScore
2.80
自引率
18.80%
发文量
504
审稿时长
2.2 months
期刊介绍: An international periodical publishing original papers, letters, review papers and short communications on nuclear chemistry. The subjects covered include: Nuclear chemistry, Radiochemistry, Radiation chemistry, Radiobiological chemistry, Environmental radiochemistry, Production and control of radioisotopes and labelled compounds, Nuclear power plant chemistry, Nuclear fuel chemistry, Radioanalytical chemistry, Radiation detection and measurement, Nuclear instrumentation and automation, etc.
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