Development of modifying additives for epoxy oligomers based on household waste polyethylene terephtalate

A. D. Kuleshova, M. Alikin, D. Panfilov, I. M. Dvorko
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Abstract

A method for synthesis of oligoester polyols (OEP) and modified resins is presented, the effect of the OEP content on the dynamic viscosity, reactivity of resins, physicochemical and mechanical properties of structural materials is studied. Materials based on epoxy-diane resin modified with glycolyzed products were obtained. It was found that the use of the developed oligomers with optimal content of epoxy-diane resin as modifier leads to an increase in some characteristics of the resulting materials: elasticity, tensile strength and elastic modulus at static bending, viability of the composition. The use of glycolysis products is advisable because it is a promising method for recycling of household waste polyethylene terephthalate. It is characterized by ease of synthesis, as well as low cost and availability of initial components, and makes it possible to increase the physical and mechanical properties of structural materials based on epoxy resins, as well as contribute to solving environmental problems.
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开发基于家用废料聚对苯二甲酸乙二醇酯的环氧低聚物改性添加剂
介绍了低聚酯多元醇(OEP)和改性树脂的合成方法,研究了 OEP 含量对动态粘度、树脂反应性、结构材料的物理化学和机械性能的影响。研究获得了基于用糖化产品改性的环氧二烷树脂的材料。研究发现,使用所开发的低聚物和最佳含量的环氧二烷树脂作为改性剂,可提高所生产材料的某些特性:弹性、拉伸强度和静态弯曲时的弹性模量、成分的可行性。使用乙二醇产品是可取的,因为它是一种很有前途的回收家用废旧聚对苯二甲酸乙二酯的方法。它的特点是易于合成,成本低,初始成分容易获得,可以提高基于环氧树脂的结构材料的物理和机械性能,并有助于解决环境问题。
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