Self-assembly of Chemically Programmed Amphiphiles into Aqueous Nanotubes with a Lipophilic Lumen.

IF 3.9 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemistry - A European Journal Pub Date : 2024-07-31 DOI:10.1002/chem.202402365
Fátima Aparicio, Irene Sancho-Casado, Paula B Chamorro, Marina González-Sánchez, Silvia Pujals, Victor Vega-Mayoral, David Gonzalez Rodriguez
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Abstract

The creation of complex hollow nanostructures with precise control over size and shape represents a great challenge in supramolecular soft materials. Here, we have further developed a bioinspired methodology for the formation of aqueous nanotubes of well-defined dimensions and pore coating through the self-assembly of amphiphiles that are chemically programmed with complementary nucleobases. These nanotubes are endowed with a hydrophobic lumen, whose diameter can be expanded as a function of the monomer length, in which apolar dyes can be efficiently encapsulated.

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将化学编程两亲化合物自组装成具有亲油腔的含水纳米管。
在超分子软材料领域,如何创造出可精确控制尺寸和形状的复杂中空纳米结构是一项巨大的挑战。在这里,我们进一步开发了一种生物启发方法,通过用互补核碱基进行化学编程的双亲化合物自组装,形成具有明确尺寸和孔涂层的水性纳米管。这些纳米管具有疏水性内腔,其直径可随单体长度的变化而扩大,无极性染料可被有效地封装在其中。
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来源期刊
Chemistry - A European Journal
Chemistry - A European Journal 化学-化学综合
CiteScore
7.90
自引率
4.70%
发文量
1808
审稿时长
1.8 months
期刊介绍: Chemistry—A European Journal is a truly international journal with top quality contributions (2018 ISI Impact Factor: 5.16). It publishes a wide range of outstanding Reviews, Minireviews, Concepts, Full Papers, and Communications from all areas of chemistry and related fields. Based in Europe Chemistry—A European Journal provides an excellent platform for increasing the visibility of European chemistry as well as for featuring the best research from authors from around the world. All manuscripts are peer-reviewed, and electronic processing ensures accurate reproduction of text and data, plus short publication times. The Concepts section provides nonspecialist readers with a useful conceptual guide to unfamiliar areas and experts with new angles on familiar problems. Chemistry—A European Journal is published on behalf of ChemPubSoc Europe, a group of 16 national chemical societies from within Europe, and supported by the Asian Chemical Editorial Societies. The ChemPubSoc Europe family comprises: Angewandte Chemie, Chemistry—A European Journal, European Journal of Organic Chemistry, European Journal of Inorganic Chemistry, ChemPhysChem, ChemBioChem, ChemMedChem, ChemCatChem, ChemSusChem, ChemPlusChem, ChemElectroChem, and ChemistryOpen.
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