Photoactive Layers based on ZnO Nanorods Obtained by Hydrothermal Synthesis for Dye-Sensitized Solar Cells

IF 1.5 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Russian Journal of Inorganic Chemistry Pub Date : 2024-08-09 DOI:10.1134/S0036023624600734
E. P. Averochkin, A. S. Steparuk, E. V. Tekshina, D. A. Krupanova, V. V. Emets, L. S. Volkova, R. M. Ryazanov, E. A. Lebedev, S. A. Kozyukhin
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Abstract

The application of zinc oxide ZnO nanorods of different heights obtained by hydrothermal synthesis as functional layers for dye-sensitized solar cells was considered. The structure, morphology, and optical properties of the nanorod layers were studied by X-ray powder diffraction, scanning electron microscopy, and optical spectroscopy. Photoanodes were fabricated using thieno[3,2-b]indole-based dyes IS 4 and IS 9. The adsorption mechanism of the dyes and ZnO structures was studied by IR spectroscopy. The efficiency of photoanodes was investigated using photoelectrochemical measurements. The dependence of the efficiency of the dye sensitized solar cells on the length of the nanorods was shown. The maximum light conversion result was obtained for a photoanode with an average nanorod height of 2.5 μm and dye IS 4 adsorbed.

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通过水热法合成获得的基于氧化锌纳米棒的光活性层,用于染料敏化太阳能电池
研究了水热合成不同高度氧化锌纳米棒作为染料敏化太阳能电池功能层的应用。利用x射线粉末衍射、扫描电子显微镜和光谱学对纳米棒层的结构、形貌和光学性能进行了研究。采用噻吩[3,2-b]吲哚基染料IS 4和IS 9制备光阳极。利用红外光谱研究了染料和氧化锌结构的吸附机理。利用光电电化学测量方法研究了光阳极的效率。结果表明,染料敏化太阳能电池的效率与纳米棒的长度有关。在平均纳米棒高度为2.5 μm且吸附染料IS 4的光阳极上,获得了最大的光转换效果。
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来源期刊
Russian Journal of Inorganic Chemistry
Russian Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
3.10
自引率
38.10%
发文量
237
审稿时长
3 months
期刊介绍: Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
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