F. Duarte Martinez, Karl Dawson, Gordon Tatlock, J. Leggett, G. Gibson, J. C. Mason-Flucke, J. R. Nicholls, A. Syed, N. Morar, S. Gray
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Abstract
This study has investigated the effect of NaCl and different gaseous environments on the stress corrosion cracking susceptibility of CMSX-4 at 550 °C. The presence of SOx leads to the rapid dissociation of NaCl into Na2SO4 and the release Cl2 and HCl, which then trigger an active oxidation mechanism and stress corrosion cracking. The incubation time for crack initiation at 690 MPa and in the presence of a sulphur containing environment is 10 min. A working hypothesis is that stress corrosion cracking occurs due to the hydrogen released at the oxide/alloy interface when metal chlorides are formed; however, this hypothesis needs to be further explored.
期刊介绍：
Oxidation of Metals is the premier source for the rapid dissemination of current research on all aspects of the science of gas-solid reactions at temperatures greater than about 400˚C, with primary focus on the high-temperature corrosion of bulk and coated systems. This authoritative bi-monthly publishes original scientific papers on kinetics, mechanisms, studies of scales from structural and morphological viewpoints, transport properties in scales, phase-boundary reactions, and much more. Articles may discuss both theoretical and experimental work related to gas-solid reactions at the surface or near-surface of a material exposed to elevated temperatures, including reactions with oxygen, nitrogen, sulfur, carbon and halogens. In addition, Oxidation of Metals publishes the results of frontier research concerned with deposit-induced attack. Review papers and short technical notes are encouraged.
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