Application of Square-Wave Stripping Voltammetry for the Analysis of Lead–Bismuth Electrodeposits

IF 1.1 4区 工程技术 Q4 ELECTROCHEMISTRY Russian Journal of Electrochemistry Pub Date : 2024-08-07 DOI:10.1134/S1023193524700198
I. A. Voronin, S. V. Sotnichuk, I. V. Kolesnik, K. S. Napolskii
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Abstract

The possibility of targeted electrodeposition of metal coatings in the lead–bismuth binary system is considered. The analysis of metal content in the deposits is performed using square-wave stripping voltammetry of solutions containing both lead and bismuth. The results are supported by the data of scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction analysis. The conditions for the formation of Pb7Bi3 (ε-phase), which is promising for the application in superconducting microelectronics, are found.

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方波剥离伏安法在铅铋电沉积物分析中的应用
摘要 研究考虑了在铅铋二元体系中有针对性地电沉积金属镀层的可能性。使用含铅和铋溶液的方波剥离伏安法分析了沉积物中的金属含量。扫描电子显微镜、能量色散 X 射线光谱和 X 射线衍射分析的数据为研究结果提供了支持。找到了 Pb7Bi3(ε相)的形成条件,该物质有望应用于超导微电子学。
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来源期刊
Russian Journal of Electrochemistry
Russian Journal of Electrochemistry 工程技术-电化学
CiteScore
1.90
自引率
8.30%
发文量
102
审稿时长
6 months
期刊介绍: Russian Journal of Electrochemistry is a journal that covers all aspects of research in modern electrochemistry. The journal welcomes submissions in English or Russian regardless of country and nationality of authors.
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