Organometallic complexes and reaction methods for synthesis: a review

IF 4.1 3区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Reviews in Inorganic Chemistry Pub Date : 2024-08-12 DOI:10.1515/revic-2024-0037
Kwestan Namiq Aziz, Karzan Mahmood Ahmed, Rebaz Anwar Omer, Aryan Fathulla Qader, Eman Ibraheem Abdulkareem
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Abstract

Organometallics are chemical compounds that consist of carbon-metal linkages. They have emerged as a result of the combination of organic and inorganic chemistry and exhibit a stable metal-carbon bond in solution. These compounds possess properties that lie between those of ionic and covalent bonds, making them highly significant in various industries. The fact that organometallics are present in all living organisms further emphasises their importance. In this overview, we will explore general reactions, such as substitution and insertion reactions, as well as different techniques for creating organometallic complexes. Additionally, we will provide a brief synthesis review of various types of organometallic complexes, including carbonyls, hydrides, alkyls, carbenes, and carbines. Organometallic compounds find extensive applications in stoichiometric chemical processes in both research and industry. Moreover, they serve as catalysts to enhance these reactions, making them more than just theoretical compounds. For example, organotin compounds are widely used as fire retardants, polymers, medications, insecticides, and stabilizers for polyvinyl chloride.
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有机金属络合物和合成反应方法:综述
有机金属是由碳-金属键组成的化合物。它们是有机化学和无机化学结合的产物,在溶液中表现出稳定的金属碳键。这些化合物具有介于离子键和共价键之间的特性,因此在各行各业中具有重要意义。有机金属存在于所有生物体内这一事实进一步强调了它们的重要性。在本综述中,我们将探讨取代反应和插入反应等一般反应,以及制造有机金属复合物的不同技术。此外,我们还将简要综述各类有机金属配合物的合成,包括羰基、氢化物、烷基、羰基和碳化物。有机金属化合物广泛应用于科研和工业领域的化学反应过程。此外,它们还可作为催化剂促进这些反应,使其不仅仅是理论上的化合物。例如,有机锡化合物被广泛用作阻燃剂、聚合物、药物、杀虫剂和聚氯乙烯的稳定剂。
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来源期刊
Reviews in Inorganic Chemistry
Reviews in Inorganic Chemistry 化学-分析化学
CiteScore
7.30
自引率
4.90%
发文量
20
审稿时长
1 months
期刊介绍: Reviews in Inorganic Chemistry (REVIC) is a quarterly, peer-reviewed journal that focuses on developments in inorganic chemistry. Technical reviews offer detailed synthesis protocols, reviews of methodology and descriptions of apparatus. Topics are treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are committed to high quality standards and rapid handling of the review and publication process. The journal publishes all aspects of solid-state, molecular and surface chemistry. Topics may be treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are commited to high quality standards and rapid handling of the review and publication process. Topics: -Main group chemistry- Transition metal chemistry- Coordination chemistry- Organometallic chemistry- Catalysis- Bioinorganic chemistry- Supramolecular chemistry- Ionic liquids
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