Scalable MOF-based mixed matrix membranes with enhanced permeation processes facilitate the scale application of membrane-based carbon capture technologies

Abstract

Mixed-matrix membranes (MMMs) leverage the processability of polymers and selectivity of Metal-Organic Frameworks (MOFs). However, they still suffer from poor interfacial compatibility and limited scalability in preparation. In certain polymers, MOFs can bridge the pores within the polymer membrane, enhancing the CO₂ adsorption and solubility properties, thus selectively boosting the CO₂ permeability. In this study, high-performance MMMs were prepared using scalable CALF-20 in combination with PIM-1. MMMs with a 5% doping level achieved CO₂ permeability up to 8003 barrer with 25% improvement in CO₂/N₂ selectivity. This enhancement was attributed to well-designed MMMs, where MOFs matched the abundant non-interconnecting pores in the PIM-1 membrane. This study represents a significant advancement towards scaling up the preparation of high-performance MOF-based MMMs for carbon capture applications.