Estimating Network Lifetime of AUN in Photo-Aging by Kinetic Modeling and “Degelation” Model

Q3 Materials Science Macromolecular Symposia Pub Date : 2024-08-16 DOI:10.1002/masy.202300247
Takato Ishida, Emmanuel Richaud, Hideaki Hagihara, Ryoma Kitagaki
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Abstract

The study develops an oxidative kinetic model of acrylic-urethane network during photo-aging. The kinetic model can track chemical reaction dynamics well and also enables to estimate the network lifetime by counting scission/crosslinking events. Estimated network lifetime is semiquantitively coincided with the one derived from different statistical approach.

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通过动力学模型和 "退化 "模型估算光老化过程中 AUN 的网络寿命
该研究建立了丙烯酸-聚氨酯网络在光老化过程中的氧化动力学模型。该动力学模型能很好地跟踪化学反应动力学,还能通过计算裂解/交联事件来估算网络寿命。估算出的网络寿命与不同统计方法得出的网络寿命基本吻合。
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来源期刊
Macromolecular Symposia
Macromolecular Symposia Materials Science-Polymers and Plastics
CiteScore
1.50
自引率
0.00%
发文量
226
期刊介绍: Macromolecular Symposia presents state-of-the-art research articles in the field of macromolecular chemistry and physics. All submitted contributions are peer-reviewed to ensure a high quality of published manuscripts. Accepted articles will be typeset and published as a hardcover edition together with online publication at Wiley InterScience, thereby guaranteeing an immediate international dissemination.
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