Sustainable Porous Heterogeneous Catalysts for the Conversion of Biomass into Renewable Energy Products

Sujan Mondal, Santu Ruidas, Sayantan Chongdar, Basudeb Saha and Asim Bhaumik*, 
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Abstract

Bioenergy possesses the potential to alleviate our energy demands while maintaining renewability and carbon neutrality. The utilization of abundant biomass sources for bioenergy production presents a significant challenge. When considering chemical processes for conversion, the development of effective catalysts becomes imperative as they play a pivotal role in biomass-to-bioenergy/biofuel conversion. In such scenarios, heterogeneous nanoporous materials emerge as crucial components for facilitating catalytic conversion. This perspective provides a comprehensive summary of biomass, including its classification, valorization processes and applications along with recent advancements in various catalytic systems utilized for transforming biomass and its intermediates into renewable energy products. We delved into the diverse classes of heterogeneous catalysts, including metal-based, metal oxide-based, silica based, hybrid catalysts, and organic polymers, highlighting their unique structural and compositional features that influence catalytic activity and selectivity. Furthermore, we discussed the importance of pore structure, surface area, and active site accessibility in enhancing catalytic performance. By examining the advantages and limitations of different catalysts, we provide insights into the rational design and optimization of porous heterogeneous catalysts for efficient and sustainable bioenergy conversion. This perspective serves as a valuable resource for researchers and engineers in the field of renewable energy, seeking to develop innovative catalyst materials for biomass valorization.

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将生物质转化为可再生能源产品的可持续多孔异构催化剂
生物能源具有缓解我们的能源需求,同时保持可再生性和碳中和的潜力。利用丰富的生物质资源生产生物能源是一项重大挑战。在考虑化学转化过程时,开发有效的催化剂势在必行,因为催化剂在生物质到生物能源/生物燃料的转化过程中发挥着关键作用。在这种情况下,异质纳米多孔材料成为促进催化转化的关键成分。本视角对生物质进行了全面总结,包括生物质的分类、价值化过程和应用,以及用于将生物质及其中间产物转化为可再生能源产品的各种催化系统的最新进展。我们深入探讨了各类异质催化剂,包括金属基、金属氧化物基、硅基、混合催化剂和有机聚合物,重点介绍了影响催化活性和选择性的独特结构和组成特征。此外,我们还讨论了孔隙结构、表面积和活性位点可及性对提高催化性能的重要性。通过研究不同催化剂的优势和局限性,我们深入了解了如何合理设计和优化多孔异质催化剂,以实现高效、可持续的生物能源转化。这一视角为可再生能源领域的研究人员和工程师提供了宝贵的资源,帮助他们开发创新的催化剂材料,实现生物质的价值化。
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