Investigations of corrosion inhibition of ethanolic extract of Dillenia suffruticosa leaves as a green corrosion inhibitor of mild steel in hydrochloric acid medium

Ukashat Mamudu , Jose Hernandez Santos , Saviour A. Umoren , Mohamad Sahban Alnarabiji , Ren Chong Lim
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Abstract

The utilization of plant extracts as environmentally friendly corrosion inhibitors has garnered considerable interest in the field of metallic corrosion protection. The primary objective of this study was to explore a new approach for utilizing Dillenia suffruticosa leaves extract (DSLE) to provide corrosion protection for mild steel (MS) in a molar hydrochloric acid solution. The phytocompounds responsible for corrosion prevention were extracted using ethanol with Soxhlet apparatus. The effectiveness of the extract as a corrosion inhibitor was evaluated through gravimetric and electrochemical methods, along with surface analysis of the corroded steel samples. This analysis involved the use of scanning electron microscopy (SEM) and Fourier-transformed infrared spectroscopy (FTIR) to examine the specimens with and without addition of the extract as inhibitor. The findings demonstrate that DSLE exhibits notable efficacy as a corrosion inhibitor for MS in an acidic environment. The inhibition efficiency (IE) demonstrates a positive correlation with the concentration of the extract, ultimately reaching a maximum value of 81.4 % at the optimum concentration of 1000 mg/L of the extract investigated. Potentiodynamic polarization data revealed that the DSLE functions as a mixed-type inhibitor.

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盐酸介质中作为低碳钢绿色缓蚀剂的 Dillenia suffruticosa 叶乙醇提取物的缓蚀效果研究
利用植物萃取物作为环境友好型缓蚀剂在金属腐蚀保护领域引起了极大的兴趣。本研究的主要目的是探索一种利用 Dillenia suffruticosa 叶提取物(DSLE)在摩尔盐酸溶液中为低碳钢(MS)提供腐蚀保护的新方法。采用索氏提取器用乙醇提取了防腐蚀的植物化合物。通过重量法和电化学法以及对腐蚀钢材样品的表面分析,对提取物作为缓蚀剂的效果进行了评估。分析中使用了扫描电子显微镜(SEM)和傅立叶变换红外光谱(FTIR)来检测添加和未添加萃取物作为抑制剂的试样。研究结果表明,DSLE 作为酸性环境中 MS 的缓蚀剂具有显著的功效。抑制效率(IE)与萃取物的浓度呈正相关,最终在 1000 mg/L 的最佳萃取物浓度下达到 81.4% 的最大值。电位极化数据显示,DSLE 是一种混合型抑制剂。
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