{"title":"Recent advances in metal cluster-containing spin-crossover coordination compounds","authors":"","doi":"10.1016/j.ccr.2024.216146","DOIUrl":null,"url":null,"abstract":"<div><p>Spin crossover (SCO) complexes are classic magnetic bistable materials with various promising potential applications, such as data storage, displays, switches, actuators and sensors. SCO clusters possess intriguing spin state topologies and provide a good platform to study multi-step SCO behavior and quantum cellular automata. This review focuses on the recent developments of discrete SCO clusters and cluster-based SCO coordination polymers. The synthesis, structural characters, SCO behaviors and other function are systematically analyzed for the representative SCO clusters. Their design principles and synthetic strategies are also summarized, which will help to design multifunctional discrete SCO clusters and cluster-based metal-organic frameworks.</p></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":null,"pages":null},"PeriodicalIF":20.3000,"publicationDate":"2024-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Coordination Chemistry Reviews","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010854524004922","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Spin crossover (SCO) complexes are classic magnetic bistable materials with various promising potential applications, such as data storage, displays, switches, actuators and sensors. SCO clusters possess intriguing spin state topologies and provide a good platform to study multi-step SCO behavior and quantum cellular automata. This review focuses on the recent developments of discrete SCO clusters and cluster-based SCO coordination polymers. The synthesis, structural characters, SCO behaviors and other function are systematically analyzed for the representative SCO clusters. Their design principles and synthetic strategies are also summarized, which will help to design multifunctional discrete SCO clusters and cluster-based metal-organic frameworks.
期刊介绍：
Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers.
The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.
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