Synthesis of anthracene-bridged expanded rosarin†

IF 2.7 3区 化学 Q1 CHEMISTRY, ORGANIC Organic & Biomolecular Chemistry Pub Date : 2024-09-25 Epub Date: 2024-08-28 DOI:10.1039/d4ob01283f
Bharti Yadav , Mangalampalli Ravikanth
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Abstract

The newly synthesized precursor 1,8-di(1H-pyrrol-2-yl)anthracene was condensed with pentafluorobenzaldehyde under acid-catalyzed conditions to afford the first example of a unique anthracenyl-bridged rosarin. The X-ray structure revealed a coil-like arrangement of three dipyrromethene moieties and three anthracenyl units in the rosarin framework, which exhibits a weak fluorescence at 676 nm.

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合成蒽键合膨松松香苷。
在酸催化条件下,新合成的前体 1,8-二(1H-吡咯-2-基)蒽与五氟苯甲醛缩合,得到了第一例独特的蒽基桥接玫瑰苷。X 射线结构显示,在玫瑰苷的框架中,三个二吡咯烷基和三个蒽基单元呈盘旋状排列,在 676 纳米波长处显示出微弱的荧光。
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来源期刊
Organic & Biomolecular Chemistry
Organic & Biomolecular Chemistry 化学-有机化学
CiteScore
5.50
自引率
9.40%
发文量
1056
审稿时长
1.3 months
期刊介绍: Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.
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