{"title":"Reactivity of the [HFe(CO)4]− hydride for the synthesis of low coordinated phosphorus derivatives","authors":"","doi":"10.1016/j.ica.2024.122336","DOIUrl":null,"url":null,"abstract":"<div><p>The reaction of [X][Hfe(CO)<sub>4</sub>] (X = mainly PPh<sub>4</sub>, but also NEt<sub>4</sub>, K and Ph<sub>3</sub>PNPPh<sub>3</sub>) with chlorophosphines for the synthesis of low coordinated phosphorus complexes is reviewed. Diphosphene (<img>P<img>P<img>), phospha-alkene (<img>P<img>C<), phospha-allene (<img>P<img>C<img>C<), and phosphide (>P) iron complexes have been in particular obtained, and characterized by <sup>31</sup>P NMR, and by X-ray diffraction in several cases.</p></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganica Chimica Acta","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0020169324004274","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
The reaction of [X][Hfe(CO)4] (X = mainly PPh4, but also NEt4, K and Ph3PNPPh3) with chlorophosphines for the synthesis of low coordinated phosphorus complexes is reviewed. Diphosphene (PP), phospha-alkene (PC<), phospha-allene (PCC<), and phosphide (>P) iron complexes have been in particular obtained, and characterized by 31P NMR, and by X-ray diffraction in several cases.
期刊介绍：
Inorganica Chimica Acta is an established international forum for all aspects of advanced Inorganic Chemistry. Original papers of high scientific level and interest are published in the form of Articles and Reviews.
Topics covered include:
• chemistry of the main group elements and the d- and f-block metals, including the synthesis, characterization and reactivity of coordination, organometallic, biomimetic, supramolecular coordination compounds, including associated computational studies;
• synthesis, physico-chemical properties, applications of molecule-based nano-scaled clusters and nanomaterials designed using the principles of coordination chemistry, as well as coordination polymers (CPs), metal-organic frameworks (MOFs), metal-organic polyhedra (MPOs);
• reaction mechanisms and physico-chemical investigations computational studies of metalloenzymes and their models;
• applications of inorganic compounds, metallodrugs and molecule-based materials.
Papers composed primarily of structural reports will typically not be considered for publication.
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