{"title":"Coordination ability of the dodecachloro-closo-dodecaborate anion [B12Cl12]2– in silver(I) complexation in the presence of S-donor ligands","authors":"","doi":"10.1016/j.ica.2024.122344","DOIUrl":null,"url":null,"abstract":"<div><p>The coordination ability of Ag<sub>2</sub>[B<sub>12</sub>Cl<sub>12</sub>] in the presence of S-containing ligands (tetrahydrothiophene, tetramethylthiourea, 1,3-diisopropyl-2-thiourea, 1,3-dithiole-2-thione) was studied. Mononuclear silver(I) complexes [Ag(L<sub>1</sub>)<sub>4</sub>]<sub>2</sub>[B<sub>12</sub>Cl<sub>12</sub>] (L<sub>1</sub> is tetrahydrothiophene) and [Ag(L<sub>2</sub>)<sub>3</sub>]<sub>2</sub>[B<sub>12</sub>Cl<sub>12</sub>] (L<sub>2</sub> is tetramethylthiourea) as well as binuclear silver(I) complexes [Ag<sub>2</sub>(L<em><sub>x</sub></em>)<sub>6</sub>][B<sub>12</sub>Cl<sub>12</sub>] (<em>x</em> = 3, 4; L<sub>3</sub> is 1,3-diisopropyl-2-thiourea, L<sub>4</sub> = 1,3-dithiole-2-thione) were isolated and studied by NMR, IR spectroscopy and single-crystal X-ray diffraction. In all complexes isolated, the perhalogenated boron cluster [B<sub>12</sub>Cl<sub>12</sub>]<sup>2–</sup> plays the role of a counterion.</p></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganica Chimica Acta","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0020169324004353","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
The coordination ability of Ag2[B12Cl12] in the presence of S-containing ligands (tetrahydrothiophene, tetramethylthiourea, 1,3-diisopropyl-2-thiourea, 1,3-dithiole-2-thione) was studied. Mononuclear silver(I) complexes [Ag(L1)4]2[B12Cl12] (L1 is tetrahydrothiophene) and [Ag(L2)3]2[B12Cl12] (L2 is tetramethylthiourea) as well as binuclear silver(I) complexes [Ag2(Lx)6][B12Cl12] (x = 3, 4; L3 is 1,3-diisopropyl-2-thiourea, L4 = 1,3-dithiole-2-thione) were isolated and studied by NMR, IR spectroscopy and single-crystal X-ray diffraction. In all complexes isolated, the perhalogenated boron cluster [B12Cl12]2– plays the role of a counterion.
期刊介绍：
Inorganica Chimica Acta is an established international forum for all aspects of advanced Inorganic Chemistry. Original papers of high scientific level and interest are published in the form of Articles and Reviews.
Topics covered include:
• chemistry of the main group elements and the d- and f-block metals, including the synthesis, characterization and reactivity of coordination, organometallic, biomimetic, supramolecular coordination compounds, including associated computational studies;
• synthesis, physico-chemical properties, applications of molecule-based nano-scaled clusters and nanomaterials designed using the principles of coordination chemistry, as well as coordination polymers (CPs), metal-organic frameworks (MOFs), metal-organic polyhedra (MPOs);
• reaction mechanisms and physico-chemical investigations computational studies of metalloenzymes and their models;
• applications of inorganic compounds, metallodrugs and molecule-based materials.
Papers composed primarily of structural reports will typically not be considered for publication.
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