Multi-million-year magmatic and hydrothermal activity is key to the formation of supergiant to behemothian porphyry copper deposits

IF 3.5 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Contributions to Mineralogy and Petrology Pub Date : 2024-09-09 DOI:10.1007/s00410-024-02167-4
Adrianna Luiza Virmond, Jörn-Frederik Wotzlaw, Rodrigo Rojas-Arancibia, David Selby, Cyril Chelle-Michou
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Abstract

Understanding the primary controls on mineral deposit formation and size is essential for sourcing the metals required by our ever-growing economy. The tonnage of porphyry copper deposits ranges five orders of magnitude but the key mechanisms and processes that modulate the size of these deposits remain enigmatic. Here, we investigate the behemothian deposits of the Chuquicamata Intrusive Complex (CIC) in northern Chile employing high-precision U–Pb and Re–Os geochronology. We resolve a complex long-lived magmatic-hydrothermal activity that lasted over 3.3 Myr. High-precision zircon petrochronology data indicate two distinct porphyry emplacement episodes, separated by 0.5 Myr, with the younger generation closely tied to the main intervals of hydrothermal mineralization. High-precision Re–Os molybdenite dates reveal a prolonged hydrothermal mineralization interval (> 2.5 Myr) that progressively migrated southwards within the CIC and continued after the end of the (apparent) magmatic activity. We show that the rate of copper precipitation varies little in nature (0.025–0.10 Mt/kyr) and is independent of the size of the deposit. Consistent with evidence from smaller deposits, our findings provide unprecedented evidence that copper endowment in porphyry copper deposits positively correlates with the timescales of magmatic and hydrothermal activity. Supergiant to behemothian deposits require multi-million-year magmatic-hydrothermal activity, linking the largest porphyry copper systems to a simple metric – the duration of magmatic-hydrothermal activity.

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数百万年的岩浆和热液活动是超巨型至巨型斑岩铜矿床形成的关键
了解矿床形成和规模的主要控制因素对于获取我们日益增长的经济所需的金属至关重要。斑岩铜矿床的吨位在五个数量级之间,但调节这些矿床规模的关键机制和过程仍然是个谜。在这里,我们采用高精度的 U-Pb 和 Re-Os 地质年代学研究了智利北部 Chuquicamata 侵入复合体(CIC)的巨型矿床。我们解析了持续时间超过 3.3 Myr 的复杂的长寿命岩浆-热液活动。高精度锆石岩石年代学数据表明,有两次截然不同的斑岩成矿事件,间隔时间为 0.5 Myr,其中较年轻的一次与热液成矿的主要区间密切相关。高精度的Re-Os辉钼矿日期显示,热液成矿时间间隔延长(2.5 Myr),在CIC内逐渐向南迁移,在(明显的)岩浆活动结束后仍在继续。我们的研究表明,铜的析出率在性质上变化不大(0.025-0.10 Mt/kyr),并且与矿床的大小无关。与较小矿床的证据一致,我们的发现提供了前所未有的证据,证明斑岩铜矿床中的铜禀赋与岩浆和热液活动的时间尺度呈正相关。超大型至巨型矿床需要数百万年的岩浆-热液活动,这将最大的斑岩铜系统与一个简单的指标--岩浆-热液活动的持续时间联系起来。
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来源期刊
Contributions to Mineralogy and Petrology
Contributions to Mineralogy and Petrology 地学-地球化学与地球物理
CiteScore
6.50
自引率
5.70%
发文量
94
审稿时长
1.7 months
期刊介绍: Contributions to Mineralogy and Petrology is an international journal that accepts high quality research papers in the fields of igneous and metamorphic petrology, geochemistry and mineralogy. Topics of interest include: major element, trace element and isotope geochemistry, geochronology, experimental petrology, igneous and metamorphic petrology, mineralogy, major and trace element mineral chemistry and thermodynamic modeling of petrologic and geochemical processes.
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