Density, Surface Tension, and Viscosity of Liquid Low‐Sulfur Manganese–Boron Steel via Maximum Bubble Pressure and Oscillating Crucible Methods

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-09-12 DOI:10.1002/srin.202400252
Matheus Roberto Bellé, Lukas Neubert, Anastasiia Sherstneva, Taisei Yamamoto, Tsuyoshi Nishi, Hidemasa Yamano, Matthias Weinberg, Olena Volkova
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Abstract

In this study, the thermophysical properties of low‐sulfur manganese–boron steel with varying boron and sulfur contents at different temperatures are investigated. Density and surface tension are measured between 1550 and 1650 °C using the maximum bubble pressure method, while viscosity is examined between 1530 and 1570 °C using an improved oscillating crucible viscometer. The methods yield results with low error, consistent with existing literature. The density of the base steel decreases from 7057 ± 25 kg m−3 at 1550 °C to 6843 ± 85 kg m−3 at 1650 °C. The addition of boron (up to 57 ppm) and sulfur (up to 130 ppm) does not significantly change the density. Sulfur, increasing from 39 to 130 ppm, reduces the surface tension from 1416 ± 12 to 1302 ± 9 mN m−1 at 1650 °C. Boron's effect on surface tension varies, possibly influenced by other elements like oxygen. Viscosity ranges from 5.74 to 6.44 mPa s, with boron and sulfur additions causing minimal changes, the largest deviation being 8%. In these results, valuable data for the simulation, modeling, control, and optimization of liquid steel processing are provided.
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通过最大气泡压力法和摆动坩埚法测定液态低硫锰硼钢的密度、表面张力和粘度
本研究调查了不同温度下不同硼和硫含量的低硫锰硼钢的热物理性质。采用最大气泡压力法测量了 1550 至 1650 ℃ 之间的密度和表面张力,而采用改进型摆动坩埚粘度计检测了 1530 至 1570 ℃ 之间的粘度。这些方法得出的结果误差很小,与现有文献一致。基体钢的密度从 1550 ℃ 时的 7057 ± 25 kg m-3 降至 1650 ℃ 时的 6843 ± 85 kg m-3。硼(高达 57 ppm)和硫(高达 130 ppm)的加入并不会显著改变密度。硫从 39 ppm 增加到 130 ppm,可将 1650 °C 时的表面张力从 1416 ± 12 mN m-1 降低到 1302 ± 9 mN m-1。硼对表面张力的影响各不相同,可能受到氧等其他元素的影响。粘度范围为 5.74 至 6.44 mPa s,硼和硫的添加造成的变化极小,最大偏差为 8%。这些结果为液态钢加工的模拟、建模、控制和优化提供了宝贵的数据。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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