Luminescence Properties of Solid-Solutions in Sr3B2O6–YbBO3 System

IF 1.2 4区 化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR Journal of Structural Chemistry Pub Date : 2024-09-04 DOI:10.1134/S0022476624080031
A. B. Kuznetsov, A. Y. Jamous, V. A. Svetlichnyi, V. S. Shevchenko, A. E. Kokh, Yu. M. Andreev, K. A. Kokh
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Abstract

The Sr3B2O6–YbBO3 diagram was constructed based on samples obtained by the solid-state synthesis. In the system YbBO3, Sr3Yb(BO3)3, Sr3Yb2(BO3)4 and Sr3B2O6 phases were identified by XRD analysis. Diffusion experiments showed formation of solid solutions between all compounds. These solid solutions demonstrate typical near-infrared luminescence in the range of 960-1020 nm, characteristic of Yb3+ and related to 2F5/2 → 2F7/2 transitions in ytterbium ions.

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Sr3B2O6-YbBO3 系统固溶体的发光特性
摘要 根据固态合成获得的样品构建了 Sr3B2O6-YbBO3 图。通过 XRD 分析确定了 YbBO3 体系中的 Sr3Yb(BO3)3、Sr3Yb2(BO3)4 和 Sr3B2O6 相。扩散实验表明,所有化合物之间都形成了固溶体。这些固溶体在 960-1020 纳米范围内显示出典型的近红外发光,这是 Yb3+ 的特征,与镱离子中的 2F5/2 → 2F7/2 转变有关。
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来源期刊
Journal of Structural Chemistry
Journal of Structural Chemistry 化学-无机化学与核化学
CiteScore
1.60
自引率
12.50%
发文量
142
审稿时长
8.3 months
期刊介绍: Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.
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