{"title":"Synthesis of the (±)-trans-Whiskey and Cognac Lactones via a Donor–Acceptor Cyclopropane Hemimalonate","authors":"Tim J. Menna, Michael A. Kerr","doi":"10.1055/s-0043-1775397","DOIUrl":null,"url":null,"abstract":"<p>Aging alcohol is a timeless process that has seen little variation since the time of its invention. Molecules stored within the wood can be extracted by the alcohol to produce unique flavors. Among these molecules exist the whiskey and cognac lactones. Herein we report a short synthesis of the <i>trans</i>-whiskey and cognac lactones using a rearrangement of cyclopropane hemimalonates.</p>","PeriodicalId":22319,"journal":{"name":"Synlett","volume":"459 1","pages":""},"PeriodicalIF":1.7000,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synlett","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1055/s-0043-1775397","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
Aging alcohol is a timeless process that has seen little variation since the time of its invention. Molecules stored within the wood can be extracted by the alcohol to produce unique flavors. Among these molecules exist the whiskey and cognac lactones. Herein we report a short synthesis of the trans-whiskey and cognac lactones using a rearrangement of cyclopropane hemimalonates.
期刊介绍：
SYNLETT is an international journal reporting research results and current trends in chemical synthesis in short personalized reviews and preliminary communications. It covers all fields of scientific endeavor that involve organic synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines and offers the possibility to publish scientific primary data.
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