Cost effective glass-ceramics containing Bi2Ti2O7 nanocrystals for photocatalytic degradation of RhB

IF 3.2 3区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS Journal of Non-crystalline Solids Pub Date : 2024-09-16 DOI:10.1016/j.jnoncrysol.2024.123229
Jinxu Jiao, Junjie Zhou, Wei Liu, Dusha Luo, Dehua Xiong, Hong Li
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Abstract

The low-cost glass-ceramics catalyst can promote the application of photocatalysis technology in water pollution treatment. This study successfully synthesized cost-effective glass-ceramics containing nano-sized spherical Bi2Ti2O7 through a glass powder crystallization method. The photocatalytic efficiency of glass-ceramics catalyst prepared by different crystallization processes was evaluated by RhB dye. Furthermore, the factors affecting the photocatalytic efficiency of glass-ceramics were analyzed by crystallization mechanism, transmission electron microscope (TEM) and X-ray photoelectron spectra (XPS). Under visible light irradiation, the glass-ceramics catalyst prepared by the best crystallization process can achieve photocatalytic degradation rate of 99.3 % within 300 min. This study shows that glass-ceramics catalyst can be rendered as one of the most suitable candidates for photocatalytic degradation of organic pollutants.

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用于光催化降解 RhB 的含 Bi2Ti2O7 纳米晶体的低成本玻璃陶瓷
低成本的玻璃陶瓷催化剂可促进光催化技术在水污染处理中的应用。本研究通过玻璃粉结晶法成功合成了含有纳米级球形 Bi2Ti2O7 的高性价比玻璃陶瓷。利用 RhB 染料评价了不同结晶工艺制备的玻璃陶瓷催化剂的光催化效率。此外,还通过结晶机理、透射电子显微镜(TEM)和 X 射线光电子能谱(XPS)分析了影响玻璃陶瓷光催化效率的因素。在可见光照射下,采用最佳结晶工艺制备的玻璃陶瓷催化剂可在 300 分钟内达到 99.3% 的光催化降解率。这项研究表明,玻璃陶瓷催化剂可作为光催化降解有机污染物的最合适候选材料之一。
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来源期刊
Journal of Non-crystalline Solids
Journal of Non-crystalline Solids 工程技术-材料科学:硅酸盐
CiteScore
6.50
自引率
11.40%
发文量
576
审稿时长
35 days
期刊介绍: The Journal of Non-Crystalline Solids publishes review articles, research papers, and Letters to the Editor on amorphous and glassy materials, including inorganic, organic, polymeric, hybrid and metallic systems. Papers on partially glassy materials, such as glass-ceramics and glass-matrix composites, and papers involving the liquid state are also included in so far as the properties of the liquid are relevant for the formation of the solid. In all cases the papers must demonstrate both novelty and importance to the field, by way of significant advances in understanding or application of non-crystalline solids; in the case of Letters, a compelling case must also be made for expedited handling.
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